User's ability to escape situation may not be absolute as their ability to escape situations may have weakness.
Roger Smith (American Dad!)
Angel (Buffy the Vampire Slayer)
Stewie Griffin (Family Guy)
Ray Breslin (Escape Plan)
Arsène Lupin III (Lupin the 3rd)
Mister Miracle (DC Comics)
Batman (DC Comics)
The Joker (DC Comics)
Catwoman (DC Comics)
Riddler (DC Comics)
John Constantine (DC/Vertigo Comics)
Baby Doll (Sucker Punch)
Deadpool (Marvel Comics)
Daredevil (Marvel Comics)
Punisher (Marvel Comics)
Mystique (Marvel Comics)
Gambit (Marvel Comics)
Mercury (Marvel Comics)
Enchantress (Marvel Comics)
Nightcrawler (Marvel Comics)
Cloak (Marvel Comics)
Spider-Man (Marvel Comics)
James Bond (James Bond series)
Sonni Griffith (The Detonator)
Richard B. Riddick (The Chronicles of Riddick)
Solid Snake (Metal Gear)
Ninja Turtles (Teenage Mutant Ninja Turtles)
Spawn (Image Comics)
Assassins (Assassin's Creed)
Chris Redfield (Resident Evil)
Ben Tennyson (Ben 10)
Zatanna (DC Comics)
Dean Winchester (Supernatural)
Sam Winchester (Supernatural)
Snake Plissken (Escape from New York)
Sonic the Hedgehog (Sonic the Hedgehog)
Boba Fett (Star Wars)
Jack Sparrow (Pirates of the Caribbean)
Jewelry Bonney (One Piece)
Spock (Star Trek)
Michael Myers (Halloween)
Sherlock Holmes (Sherlock Holmes)
Peyton Westlake (Darkman)
Son Goku (Dragon Ball)
Shiki (One Piece); was the first prison in history to escape the imperturbable under sea prison, Impel Down
Monkey D. Luffy (One Piece); escaped the imperturbable under sea prison, Impel Down
Karl Ruprecht Kroenen (Hellboy)
Jill Valentine (Resident Evil)
Buffy Summers (Buffy the Vampire Slayer)
Faith Lehane (Buffy the Vampire Slayer)
Angel (Buffy the Vampire Slayer)
Link (The Legend of Zelda)
Jason Voorhees (Friday the 13th)
Mugen (Samurai Champloo)
Max Tennyson (Ben 10)
Mega Man X (Mega Man X)
Raziel (Legacy of Kain)
Neo (The Matrix)
Ashley "Ash" J. Williams (The Evil Dead series)
Yorick Brown (Y: The Last Man); survived a plague that wiped out all beings with the Y chromosome and remains fertile. He is never caught by female captors due a mix of this and his Supernatural Self-Preservation.
Roger Smith (American Dad!) violently escaped the Bang Kwang Prison despite having all four limbs shackled in an undersea isolation cell with mines, brutally slaughtering 24 guards to build a boat out of their corpses.
Angel (Buffy the Vampire Slayer) easily slipping out of shackles.
The Joker (DC Comics) has escape Arkham Asylum, Blackgate Prison, the Slab multiple times.
Catwoman's (DC Comics) seductiveness is surpassed only by her intelligence.
Arsene Lupin (Lupin the 3rd) has a knack for escaping precarious situations.
Mister Miracle (DC Comics) in a deep sea jam.
Sonni (The Detonator) moments before escaping his handcuffs and beating up the guards.
Riddick (The Chronicles of Riddick) has a "knack for escape."
No matter how many times DJ Octavio (Splatoon) is imprisoned in a snow globe, he can always escape.
Yorick Brown (Y: the Last Man) has a hobby for Escape Artistry.
Shiki, the Golden Lion (One Piece) was the first prisoner to escape from the great under sea prison Impel Down, by cutting off his own shackled legs.
Responsible for leading the very first mass-riot within Impel Down, Monkey D. Luffy (One Piece) along with Emporio Ivankov, Inazuma, Buggy, Daz Bones, Crocodile, Jinbe, Galdino, and 233 other prisoners, is responsible for the first-ever mass breakout in the jail's history.
The Sarlacc could never hold Boba Fett (Star Wars). Thanks to his iron will and Mandalorian armor, Fett was able to fight his way out of the beast's belly.
Droopy Dog (Droopy series) can escape any kinds of captivity by simply appearing behind the person who is trying to bind or imprison him.