Homer Simpson (The Simpsons) was so skilled with his gun that he was able to turn on the TV by shooting it at the right places.
Alice Fuji (Arachnid) using her Spider's Thread, a pistol that fires a hooked blade with vast amounts of thread attached, and controls the trajectory of the blade with great precision to create traps, thanks to her Congenital Excessive Concentration.
Suì-Fēng (Bleach) firing her Jakuhō Raikōben, a powerful missile launcher, with surprisingly accurate aim, considering she is a close-quarter combat assassin specialist.
Lille Barro's (Bleach) X-Axis transforms his rifle's ammunition into simply piercing any and everything between the muzzle and the target, and he can do so with tremendous accuracy.
Danjō Kōga (Basilisk) specializes in needles, hiding them in his mouth and spitting them with great accuracy and force, piercing through armor and vital points.
Tenzen Yakushiji (Basilisk) spitting poisoned needles with great accuracy and precision, carving the characters for "Iga" on Kagerō's body.
Haku (Naruto) using needles for combat, whether for throwing accurately, slashing in hand, or even forming them as the Thousand Flying Water Needles of Death.
Anko Mitarashi (Naruto) throwing toothpicks with such accuracy and precision, she managed to engrave the Konoha mark on a tree.
Shizune (Naruto) using Prepared Needle Shot to fire poisoned needles at her opponents with efficient and stealthy precision.
Sasuke Uchiha (Naruto) throwing his Chidori Senbon to throw solidified electrical needles at his opponent with lethal accuracy and precision.
Armed with his trusty bow, Link (Legend of Zelda series) is capable of nailing his enemies near or far with magic arrows.
Zelda (Legend of Zelda series) is a master archer who became essential in helping Link sniping down the final enemy.
Train Heartnet (Black Cat) is a master marksman via his great eyesight and master firing skills.
Durham Glaster (Black Cat) can use his Tao abilities to guide his bullets.
Beluga J. Heard (Black Cat) wielding Verethragna bazooka with deadly skills.
Toki (Code: Breaker) uses his powerful left eye and magnetically charged guns for lethal firing skills.
Alucard (Hellsing) is known for being able to shoot long-range targets while looking in the opposite direction.
The Creeper (Jeepers Creepers) can throw knives and other throwing weapons with such accuracy that they appear to move of their own accord.
Wesley Wyndam-Pryce (Buffy the Vampire Slayer/Angel) has such skill with firearms that he can hit small targets while performing acrobatics.
Shadow the Hedgehog (Sonic the Hedgehog) wielding a gun.
Vash the Stampede (Trigun)
Revolver Ocelot (Metal Gear Solid) is an expert marksman specializing in the Colt Single Action Army revolver.
Jericho Cross (Darkwatch)
Kevin Keene (Captain N: The Game Master)
Legolas (The Lord of the Rings) can shoot arrows with such inhuman accuracy, that he hardly ever misses his target.
Turok (Turok: Dinosaur Hunter)
Among Buffy Summers' (Buffy the Vampire Slayer) Slayer powers is incredible skill with ranged weaponry such as crossbows.
Usopp (One Piece) is known as one of the best snipers in the One Piece world
Laguna Loire (Final Fantasy VIII/Dissidia)
Bullseye (Marvel) is a master of this ability.
Tasha Godspell (Witch Hunter) is called the Magical Marksman for a reason.
Allan Quatermain (Allan Quatermain series/The League of Extraordinary Gentlemen) is a virtually unparalleled marksman.
Kaname can shoot at a tanker hundreds of yards away from the top of a cliff, while traveling many mph.
Nack the Weasel a.k.a Fang the Sniper (Sonic the Hedgehog) is an expert marksman and sniper
Starrk has proven to be quite skilled with his pistols when released.
Reborn (Katekyo Hitman Reborn!) wielding his gun. Reborn is known for his Dying Will Bullet.
Gene (Metal Gear Solid: Portable Ops) can throw knives with deadly accuracy and precision.
With his spear gun, Dimitri has proven to be an excellent marksman.
Tennessee "Kid" Cooper (Sly Cooper) carries a six-shot revolver with a hooked handle as his Cooper Cane, with which he demonstrates spectacular gun-slinging skills.
Dante's skill with firearms is impeccable. He has displayed enough accuracy to hit targets as small as the pommel of his sword; shoot his opponents' bullets out of mid-air; and hit the same target over and over with such unerring precision that his bullets stack on top of each other.
Tsuruhime (Valkyrie Crusade) always hits her target.
Isabel (Valkyrie Crusade)
Failnaught (Valkyrie Crusade)
Gae Bulg (Valkyrie Crusade)